The X. and the V. Standards
The international CCITT ("Cunsultative Committee for Telegraphy and Telephony" - since renamed to ITU-T) created all those X. and V. standards that you keep seeing.
The X Standards (X.21, X.25, X.121, etc)
http://www.itu.int/rec/recommendation.asp?type=products&parent=T-REC-x
The V Standards (V.32, V.90, V.35, etc)
http://www.itu.int/rec/recommendation.asp?type=products&parent=T-REC-v
NOTE1: if you must get the details, click on the link for that particular standard, and if it is still active, you can buy a PDF file describing it
Other CCITT Standards (such as R. etc)
You can use the given link and replace the letter at the end for other standards/ For example, there is an entire set of "R" standards, and the link would be the same as for X, except replace the X with R :
http://www.itu.int/rec/recommendation.asp?type=products&parent=T-REC-R